郭圣荣:男,汉族,江西樟树人,1976年4月出生。中共党员,博士,教授。2014年到美国威斯康辛大学麦迪逊分校进行访学一年,2016年9月获得博士学位。主持浙江省自然科学基金项目3项,参与国家自然科学基金项目1项,主持市科技局项目2项,近5年来,在Angew. Chem. Int. Ed., Org.Lett., Chem. Commun., Synlett, Tetrahedron. Lett等重要专业学术刊物上发表研究论文20余篇,其中SCI一区论文4篇。先后获得过“丽水市138人才”、丽水学院“先进工作者”、“教坛新秀”及丽水市优秀共产党员等荣誉。担任多家公司的技术顾问,社会服务能力较强。 | |
主要研究方向: 1.有机催化与合成方法学 2.有机硫功能小分子合成 3.三光气与异氰酸酯开发与应用 | |
主持的科研项目: 1.过渡金属催化的若干C-S键活化与转化研究 浙江省自然科学基金项目(LY16B020018),2016.01-2018.128万 (主持 结题) 2.可见光促进硫自由基参与及催化串联反应研究浙江省自然科学基金项目(LY19B020001),2019.01-2021.129万 (主持 进行中) 3.海绵”型竹炭的研发与应用研究。丽水市科技局高层次人才培养项目(2018GCCRC),2018.6-2020.6,5万 项目负责人; 4.萘基异氰酸酯的合成工艺研究与综合应用开发。浙江丽水有邦新材料有限公司,2017.1-2019.12,20万 项目负责人 | |
代表性科研成果 论文: 1.Shengrong Guo,Yanqin Yuan, Jiannan Xiang. Metal-Free Oxidative C(sp3)-H Bond Thiolation of Ethers with Disulfides[J]. Org.Lett.2013, 15(18), 4654–4657. 2.Shengrong Guo, Weimin He, Jiannan Xiang, Yanqin Yuan. Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides[J]. Chem. Commun.,2014, 50, 8578-8581. 3.Hao-Yuan Wang, Ka Yang, Scott R. Bennett, Sheng-rong Guo,* and Weiping Tang* Iridium-Catalysed Dynamic Kinetic Isomerization: Expedient Synthesis of Carbohydrates from Achmatowicz Rearrangement Products[J]. Angew. Chem. Int. Ed., 2015, 54, 8756-8759. 4.Shengrong Guo, Weimin He, Jiannan Xiang, Yanqin Yuan. Ruthenium-catalyzed direct thiolation of alkanes and ethers using arylsulfonyl chlorides as a sulfur source[J]. Tetrahedron Lett., 2015, 56, 2159–2162. 5.Shengrong Guo, Yanqin Yuan, Jiannan Xiang. Copper-catalyzed oxidative alkenylation of C(sp3)–H bonds via benzyl or alkyl radical addition to β-nitrostyrenes [J]. New J.Chem., 2015, 39, 3093-3097. 6.Yanqin Yuan Shengrong Guo, Jiannan Xiang. Cu(OAc)2-catalyzed thiolation of acyl C-H bond with thiols using TBHP as an oxidant[J]. Synlett, 2013, 24, 443-448. 7.Shengrong Guo, Weimin He, Jiannan Xiang, Yanqin Yuan. Palladium-catalyzed direct thiolation of ethers with sodium sulfinates[J]. Tetrahedron Lett., 2014, 55, 6407-6410. 8.Sheng-rong Guo, Yan-qin Yuan. Copper-Catalyzed Alkenylation of Alcohols with β-nitrostyrenes via a Radical Addition-Elimination Process[J]. Synlett, 2015, 26, 1961- 1968. 9.Shengrong Guo, S. K. Pailla, Y.-Q. Yuan, M.-H. Yang, Gold-catalyzed, iodine(III)-mediated direct acyloxylation of the unactivated C(sp3)–H bonds of methyl sulfides[J]. Eur. J. Org. Chem. 2016, 4260–4264. 10.Shengrong Guo, S. K. Pailla, M.-H. Yang, Recent advances of oxidative radical cross-coupling reactions: direct α-C(sp3)–H bond functionalization of ethers and alcohols[J]. Adv. Synth. Catal.2017, 359, 2 – 25. 11.Y.-q. Yuan, P. S. Kumar, C.-n. Zhang, M.-h. Yang, Sheng-rong Guo* Aerobic thiyl radical addition/cyclization of N-methacryloyl benzamides for the synthesis of isoquinoline-1,3(2H,4H)-dione derivatives[J]. Org. Biomol. Chem., 2017, 15, 7330–7338. 12.Y.-q. Yuan, P. S. Kumar, Sheng-rong Guo * Metal-Free Ammonium Iodide Catalyzed Oxidative Dehydrocoupling of Silanes with Alcohols[J].. Synlett, 2017, 28, 1620–1623. 13.Sheng-rong Guo, P. S. Kumar, Y.Q. Yuan, M.H. Yang, Palladium catalyzed aroylation of NH-sulfoximines with aryl halides using chloroform as the CO precursor[J]. Tetrahedron Letters, 58 (2017) 2681–2684. 14.郭圣荣 袁艳琴一种用硫酚或硫醇制备亚磺酸酯的方法,发明专利(ZL 201610916711.2) 获奖: 1.郭圣荣. 2017年丽水市优秀共产党员; 2.郭圣荣. 2016年度丽水学院先进工作者; 3.郭圣荣. 2013年入选丽水市138人才第二层次培养人员。 |